Airs: 4:30am - 5:00am on itv
Virgil and Grandma are out resupplying Thunderbird 2 when a distress call comes in. A mine is in danger of collapsing in the desert. When Virgil goes to help the workers, he gets caught in a massive sandstorm and it is up to Grandma to save the day.
Airs: 7:00am - 7:30am on Disney XD
Spider-Man is targeted by a new costumed figure named Screwball for a series of online prank videos which block him from fighting crime.
DuckTales Season 1, Episode 8
Airs: 8:00am - 8:30am on Disney XD
In a lost pyramid, Louie interprets a pharaoh's prophecy to his advantage, forcing Scrooge and Launchpad to convince a group of living mummies to rescue him.
Airs: 9:30am - 10:00am on Cartoon Network
The Autobots' pursuit of Steeljaw hits an unexpected roadblock when Strongarm's old mentor Detective Dropforge arrives from Cybertron with orders to arrest the Bee Team.
Airs: 9:30am - 10:00am on Disney Channel
Elena invites a princess from a neighboring kingdom to Avalor hoping to repair an old alliance.
Airs: 10:00am - 10:15am on Cartoon Network
When members of the Justice League are affected by the Phantom Zone ray and become phantom-like, their only hope for freedom is to somehow get a message to Booster Gold.
Airs: 11:00am - 11:30am on HUB
When Sunburst discovers the lost journal of Starswirl the Bearded, Twilight becomes obsessed with saving her magical idol from a thousand-year-old prison.
Airs: 11:30am - 12:00pm on HUB
With Starswirl and the other Pillars of Old Equestria back from limbo (where they've been trapped for a thousand years), Twilight and her friends must work together to defeat the Pony of Shadows.
Airs: 3:15pm - 4:45pm on BBC One
Spiders, witches, broomsticks and ghosts take up residence in the ballroom, as the dancing contest's traditional Halloween special arrives. Entering the sixth weekend of the contest, the pack of couples has been whittled down to 11, and judges Shirley Ballas, Darcey Bussell, Bruno Tonioli and Craig Revel Horwood will be looking for the pro-celebrity duos to deliver suitably spooky performances if they are to earn the highest scores and boost their chances of finding themselves in a dance-off on Sunday. Tess Daly and Claudia Winkleman present.
Airs: 4:00pm - 5:00pm on ITV1
Casualty Season 32, Episode 10
Airs: 5:00pm - 5:50pm on BBC One
Dylan helps a patient who was placed into foster care to protect her from her mother's abusive partner, and the encounter makes him realise that he must do what it right for Sanosi - even if it isn't always the easy thing. Meanwhile, Elle's new beau Marty receives a rude awakening when her sons catch them together in bed, and what was already a tense situation becomes even more awkward when he turns up at the hospital seeking help with a particularly sensitive problem
Gunpowder Season 1, Episode 2
Airs: 5:10pm - 6:10pm on BBC One
As the king's network of spies close in on them, Catesby and Wintour attempt to raise an army for their plot across mainland Europe. Returning to London with Guy Fawkes in tow, Catesby assembles his gang of plotters for the first time. They know they must act fast, and the plan is formed - they will strike next week, 5 November, at the opening of Parliament.
Airs: 6:00pm - 7:00pm on ITV1
Jonathan Ross chats with legendary singer Tina Turner, UFC champion Conor McGregor, presenter and writer Clare Balding and actor Andrew Garfield, while the award-winning Plan B performs live in the studio.
Airs: 8:00pm - 9:00pm on TNT
Kelly and Aaron Sam head to Lake Charles, Louisiana to investigate the shocking murder of a young man who was gunned down in his car after attending church on Palm Sunday.
Airs: 9:00pm - 9:30pm on BBC America
While investigating the 40-year-old case of the two dead bodies, Dirk and the gang are surprisingly joined by Bart who relays that she was assaulted and spins the case in a new direction, an investigation into Suzie Boreton.
Airs: 11:59pm - 12:59am on Netflix
After Will sees something terrible on trick-or-treat night, Mike wonders whether Eleven's still out there. Nancy wrestles with the truth about Barb.