Mark and Digger get raided by cops forcing them to flee across state lines. Tickle and the Laws assemble a new mega operation as Josh heads their way with a truckload of fruit. Mike and Jerry build the courage to return to the scene of their own crime.
JB leads Mark and Digger to the secret site of Popcorn Sutton's infamous last run; Mike and Jerry's attempt to make a still from a used whiskey barrel blows up in their faces; Tickle, Josh and the Laws get ambushed, forcing them to run for the hills.
Tickle and the Laws escape from a raid on their still site only to discover that Josh is missing; Tim and Howard tackle a gas shortage with a high-proof solution; Mike and Jerry rebuild their oak barrel pot still after blowing up their first attempt.
Mark and Digger hit a wall transporting Tennessee water to Popcorn's North Carolina still site. Mark and Huck attempt to make fortified wine the old-fashioned way - with their feet.
When Mark and Digger ask to run on commercial property, the answer is as shocking as the results. Mike and Jerry turn blueberries into top-shelf brandy, but it's the mash that's worth celebrating. Richard chases the green fairy to make backwoods absinthe.
Mark and Digger attempt to reroute a limestone creek over a mountain and onto private property; Mike drops a bombshell on Jerry while making backwoods blueberry champagne.
Mark and Digger retrieve their sea-aged whiskey only to discover how easily it slips through their fingers. Richard and Craig run into trouble upsizing absinthe production. Tickle and the Laws look to moonshine history to get their season on track.
Mark and Digger search in an unlikely location for the ideal spot to sea-age their Tennessee Whiskey. A wrong turn earns Josh his next broken bone. When Jerry gets rushed to the ER, his partner is forced to figure out a complex recipe without him.
Mark and Digger revisit the abandoned theme park of their misspent youth and convert a carnival ride into a whiskey-aging machine.
Mark and Digger whip up a high-gravity southern dessert while Tim puts a backwoods ritual onto store shelves; Amanda helps Mark and Huck...
When Josh devises a formula for a profitable hard seltzer, he must convince Tickle and the Laws to contribute their valuable peach brandy to a risky enterprise; Mark and Digger attempt to turn a windfall of scuppernong grapes into Appalachian cognac.
Amanda helps Mark and Huck use science to infuse fresh-picked pears into their traditional corn shine. Richard teams up with Mark and Digger to make cherry cognac. Jerry returns from his close call to help Mike build a waterfall still site in Tennessee.